Task Group on Atmospheric Chemical Kinetic Data Evaluation

Summary Pressure Independent

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ID Reactions k298
cm³ molecule-1s-1
Δlogk Temp. dependence of k/cm³ molecule-1s-1 Δ(E/R)/ka Temperature range
Ox1O + O2 + MO3 + M   kd
Ox2O + O3O2 + O2   8.0e-150.088.0e-12*exp(-2060/T)200200-400
Ox_VOC8O3 + α-pineneproducts   9.4e-170.158.05e-16*exp(-640/T)300240-370
NO3_VOC46NO3 campheneproducts   6.6e-130.1
Ox_VOC19O3 + β-pineneproducts   1.9e-170.251.35e-15*exp(-1270/T)300290-370
Ox_VOC20O3 + limoneneproducts   2.1e-160.12.8e-15*exp(-770/T)300290-370
Ox_VOC21O3 + campheneproducts   6.8e-190.3
Ox_VOC24O3 + β-myrceneproducts   4.6e-160.22.65e-15*exp(-520/T)300290-320
Ox_VOC22O3 + 2-careneproducts   2.4e-160.2
Ox_VOC23O3 + 3-careneproducts   4.8e-170.2
Ox_VOC26O3 + α-phellandreneproducts   3.0e-150.2
Ox_VOC25O3 + β-ocimeneproducts   4.9e-160.2
Ox_VOC27O3 + β-phellandreneproducts   5.0e-170.3
Ox_VOC29O3 + α-terpineneproducts   1.9e-140.2
Ox_VOC28O3 + sabineneproducts   8.2e-170.15
Ox_VOC30O3 + γ-terpineneproducts   1.5e-160.3
Ox_VOC31O3 + terpinoleneproducts   1.6e-150.15
Ox_VOC32O3 + β-caryophylleneproducts   1.2e-140.15
OX_VOC34O3 + α-copaeneproducts   1.5e-160.3
Ox_VOC35O3 + α-farneseneproducts   5.9e-160.33.5e-12*exp(-2590/T)500290-320
Ox_VOC36O3 + β-farneseneproducts   5.6e-160.251.5e-12*exp(-2350/T)500290-320
Ox_VOC38O3 + isolongifoleneproducts   1.0e-170.3
Ox_VOC39O3 + longifoleneproducts   < 5e-19-
HOx_VOC51HO2 + CH3O2O2 + CH3OOH
O2 + HCHO + H2O   
k = 5.2e-12
k1 = k*0.9
k2 = k*0.1
0.2
0.1
0.1
k = 3.8e-13*exp(780/T)
k1 = (k-k2)
k2 = k/(1+ 498*exp(-1160/T))
200

500
220-298